Comic suggestions with male superhero and female supervillain who fall in love, like Spiderman X Black Cat?

I've been watching and reading a bunch of Spider-man lately, and I've been really enjoying Spiderman X Black Cat, so I wanted more suggestions.

Things I specifically want:

• superhero male, supervillain female

• start as enemies but become lovers

• preferably both are humans

• extra plus if there's a school setting like Spiderman

• no manga, preferably Marvel. I don't like DC much. Also open to other comics

Does anyone have recs? (I've also read a lot of popular series so I already read or watched SpidermanXBlack Cat, BatmanXCatwoman, etc)